Browsing by Author "Gunathilake, Samodha S."
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Item Nitrogen Containing Graphene-Like Structures from Pyrolysis of Pyrimidine Polymers for Polymer/graphene Hybrid Field Effect Transistors(Royal Soc Chemistry, 2014-09-02) Gunathilake, Samodha S.; Huang, Peishen; Bhatt, Mahesh P.; Rainbolt, Elizabeth A.; Stefan, Mihaela C.; Biewer, Michael C.; 55039821 (Stefan, MC); Stefan, Mihaela C.; Biewer, Michael C.Nitrogen containing graphene like structures were obtained by the pyrolysis of two pyrimidine polymers at 600 degrees C. Pyrimidine polymers were prepared by the base catalyzed aldol condensation reactions between 2-decyloxy-4,6-dimethylpyrimidine and two aromatic dialdehydes. Pyrolyzed products were shown to have a graphitic structure by Raman spectroscopy, scanning electron microscopy, and powder X-ray diffraction studies. The presence of nitrogen in the graphitic structures was proved by elemental analysis and energy dispersive X-ray analysis experiments. Fluorescence quenching experiments with poly(3-hexylthiophene) (P3HT) showed that the resultant graphitic material can act as an acceptor. These materials were tested in P3HT/graphene hybrid field effect transistors which exhibited higher mobilities and comparable on/off ratios compared to P3HT only devices.Item Synthesis and characterization of novel semiconducting polymers containing pyrimidine(Royal Soc Chemistry, 2013-02-27) Gunathilake, Samodha S.; Magurudeniya, Harsha D.; Huang, Peishen; Nguyen, Hien; Rainbolt, Elizabeth A.; Stefan, Mihaela C.; Biewer, Michael C.; 55039821 (Stefan, MC); Stefan, Mihaela C.; Biewer, Michael C.The acidic methyl protons of 4,6-dimethylpyrimidines can be easily deprotonated with a base to generate a resonance stabilized carbanion which can be used as a substrate for aldol condensation reactions. A series of novel conjugated polymers were synthesized by the aldol condensation reaction of 2-decyloxy-4,6-dimethylpyrimidine with various aromatic dialdehydes.