Show simple item record

dc.contributor.authorHu, Zhichaoen_US
dc.contributor.authorTan, Kuien_US
dc.contributor.authorLustig, William P.en_US
dc.contributor.authorWang, Haoen_US
dc.contributor.authorZhao, Yonggangen_US
dc.contributor.authorZheng, Chongen_US
dc.contributor.authorBanerjee, Debasisen_US
dc.contributor.authorEmge, Thomas J.en_US
dc.contributor.authorChabal, Yves J.en_US
dc.contributor.authorLi, Jingen_US
dc.date.accessioned2015-01-21T23:24:42Z
dc.date.available2015-01-21T23:24:42Z
dc.date.created2014-08-27
dc.identifier.citationHu, Zhichao, Kui Tan, William P. Lustig, Hao Wang, et al. 2014. "Effective sensing of RDX via instant and selective detection of ketone vapors." Chemical Science 5(12): 4873-4877.en_US
dc.identifier.issn2041-6520en_US
dc.identifier.urihttp://hdl.handle.net/10735.1/4281
dc.description.abstractTwo new luminescent metal-organic frameworks (LMOFs) were synthesized and examined for use as sensory materials. Very fast and effective sensing of RDX was achieved by vapor detection of a cyclic ketone used as a solvent in the production of plastic explosives. The effects of porosity and electronic structure of the LMOFs on their sensing performance were evaluated. We demonstrate that the optimization of these two factors of an LMOF can significantly improve its sensitivity and selectivity. We also elucidate the importance of both electron and energy transfer processes on the fluorescence response of a sensory material.en_US
dc.description.sponsorshipUS Department of Energy grant (DE-FG02-08ER-4649)en_US
dc.relation.urihttp://dx.doi.org/10.1039/c4sc02157fen_US
dc.rights©2014 The Royal Society of Chemistryen_US
dc.subjectKetonesen_US
dc.subjectVaporsen_US
dc.subjectRDX (Cyclonite)en_US
dc.subjectDetectorsen_US
dc.subjectFluorescenceen_US
dc.titleEffective Sensing of RDX via Instant and Selective Detection of Ketone Vaporsen_US
dc.type.genrearticleen_US
dc.source.journalChemical Scienceen_US
dc.identifier.volume5en_US
dc.identifier.issue12en_US
dc.contributor.ISNI0000 0000 4239 3958 (Chabal, YJ)en_US
dc.contributor.LCNA89624105 (Chabal, YJ)en_US


Files in this item

Thumbnail
Thumbnail
Thumbnail

This item appears in the following Collection(s)

Show simple item record