• Login
    View Item 
    •   Treasures Home
    • Academic Schools and Programs
    • School of Natural Sciences and Mathematics
    • NSM Faculty Research
    • Balkus, Kenneth J.
    • View Item
    •   Treasures Home
    • Academic Schools and Programs
    • School of Natural Sciences and Mathematics
    • NSM Faculty Research
    • Balkus, Kenneth J.
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Transition from a 1D Coordination Polymer to a Mixed-Linker Layered MOF

    Thumbnail
    View/Open
    Link to Article (165.8Kb)
    Author
    Vizuet, Juan P.
    Howlett, Thomas S.
    Lewis, Abigail L.
    Chroust, Zachary D.
    McCandless, Gregory T.
    Balkus, Kenneth J.
    Metadata
    Show full item record
    Abstract
    Abstract
    A novel copper(II) metal-organic framework (MOF) has been synthesized by modifying the reaction conditions of a 1D coordination polymer. The 1D polymer is built by the coordination between copper and 2,2′-(1H-imidazole-4,5-diyl)di-1,4,5,6-tetrahydropyrimidine (H-L1). The geometry of H-L1 precludes its ability to form extended 3D framework structures. By adding 1,4-benzenedicarboxylic acid (H 2 BDC), a well-studied linker in MOF synthesis, we achieved the transition from a 1D polymer chain into porous 2D layered structures. Hydrogen bonding between L1 and BDC directs the parallel stacking of these layers, resulting in a 3D structure with one-dimensional channels accessible by two different pore windows. The preferred growth orientation of the crystal produces prolonged channels and a disparity in pore size distribution. This in turn results in slow diffusion processes in the material. Furthermore, an isoreticular MOF was prepared by substituting the BDC linker by 2,6-naphthalenedicarboxylic acid (H₂NDC). © 2019 American Chemical Society.
    Description
    Due to copyright restrictions full text access from Treasures at UT Dallas is restricted to current UTD affiliates (use the provided Link to Article).
    URI
    https://hdl.handle.net/10735.1/7157
    Collections
    • Balkus, Kenneth J.

    DSpace software copyright © 2002-2016  DuraSpace
    Contact Us | Send Feedback
    Theme by 
    Atmire NV
     

     

    Browse

    All of TreasuresCommunities & CollectionsBy Issue DateAuthorsTitlesSubjectsThis CollectionBy Issue DateAuthorsTitlesSubjects

    My Account

    Login

    DSpace software copyright © 2002-2016  DuraSpace
    Contact Us | Send Feedback
    Theme by 
    Atmire NV