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dc.contributor.authorVizuet, Juan P.
dc.contributor.authorHowlett, Thomas S.
dc.contributor.authorLewis, Abigail L.
dc.contributor.authorChroust, Zachary D.
dc.contributor.authorMcCandless, Gregory T.
dc.contributor.authorBalkus, Kenneth J.
dc.date.accessioned2020-01-17T22:39:50Z
dc.date.available2020-01-17T22:39:50Z
dc.date.created2019-03-29
dc.identifier.issn0020-1669
dc.identifier.urihttps://hdl.handle.net/10735.1/7157
dc.descriptionDue to copyright restrictions full text access from Treasures at UT Dallas is restricted to current UTD affiliates (use the provided Link to Article).
dc.description.abstractA novel copper(II) metal-organic framework (MOF) has been synthesized by modifying the reaction conditions of a 1D coordination polymer. The 1D polymer is built by the coordination between copper and 2,2′-(1H-imidazole-4,5-diyl)di-1,4,5,6-tetrahydropyrimidine (H-L1). The geometry of H-L1 precludes its ability to form extended 3D framework structures. By adding 1,4-benzenedicarboxylic acid (H 2 BDC), a well-studied linker in MOF synthesis, we achieved the transition from a 1D polymer chain into porous 2D layered structures. Hydrogen bonding between L1 and BDC directs the parallel stacking of these layers, resulting in a 3D structure with one-dimensional channels accessible by two different pore windows. The preferred growth orientation of the crystal produces prolonged channels and a disparity in pore size distribution. This in turn results in slow diffusion processes in the material. Furthermore, an isoreticular MOF was prepared by substituting the BDC linker by 2,6-naphthalenedicarboxylic acid (H₂NDC). © 2019 American Chemical Society.
dc.description.sponsorshipRobert A. Welch foundation (Grant No. AT-1153).
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.relation.urihttps://dx.doi.org/10.1021/acs.inorgchem.9b00077
dc.rights©2019 American Chemical Society
dc.subjectCopper
dc.subjectPolymers
dc.titleTransition from a 1D Coordination Polymer to a Mixed-Linker Layered MOF
dc.type.genrearticle
dc.description.departmentSchool of Natural Sciences and Mathematics
dc.identifier.bibliographicCitationVizuet, J. P., T. S. Howlett, A. L. Lewis, Z. D. Chroust, et al. 2019. "Transition from a 1D Coordination Polymer to a Mixed-Linker Layered MOF." Inorganic Chemistry 58(8): 5031-5041, doi: 10.1021/acs.inorgchem.9b00077
dc.source.journalInorganic Chemistry
dc.identifier.volume58
dc.identifier.issue8
dc.contributor.utdAuthorVizuet, Juan P.
dc.contributor.utdAuthorHowlett, Thomas S.
dc.contributor.utdAuthorLewis, Abigail L.
dc.contributor.utdAuthorChroust, Zachary D.
dc.contributor.utdAuthorMcCandless, Gregory T.
dc.contributor.utdAuthorBalkus, Kenneth J.
dc.contributor.ORCID0000-0003-1142-3837 (Balkus, KJ)


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