Utilization of a Meldrum's Acid Towards Functionalized Fluoropolymers Possessing Dual Reactivity for Thermal Crosslinking and Post-Polymerization Modification

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Abstract

New thermally cross-linkable and/or post-functionalizable perfluorocyclobutyl (PFCB) polymers containing Meldrum's acid moieties have been successfully prepared via the thermal cyclopolymerization of a new Meldrum's acid functionalized aromatic trifluorovinyl ether (TFVE) monomer.

Description

Includes supplementary information

Keywords

Polymers, Monomers, Thiol–Trifluorovinyl Ether (TFVE), Fluoropolymers, Ketenes

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Funded in part by the Welch Foundation (grant AT-0041); National Science Foundation (CEHMS: NSF-1/UCRC grant 1035024) and (NMR grant CHE-1126177)

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©2015 The Royal Society of Chemistry. This article may not be further made available or distributed.

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