Transition from a 1D Coordination Polymer to a Mixed-Linker Layered MOF

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dc.contributor.ORCID0000-0003-1142-3837 (Balkus, KJ)
dc.contributor.authorVizuet, Juan P.
dc.contributor.authorHowlett, Thomas S.
dc.contributor.authorLewis, Abigail L.
dc.contributor.authorChroust, Zachary D.
dc.contributor.authorMcCandless, Gregory T.
dc.contributor.authorBalkus, Kenneth J.
dc.contributor.utdAuthorVizuet, Juan P.
dc.contributor.utdAuthorHowlett, Thomas S.
dc.contributor.utdAuthorLewis, Abigail L.
dc.contributor.utdAuthorChroust, Zachary D.
dc.contributor.utdAuthorMcCandless, Gregory T.
dc.contributor.utdAuthorBalkus, Kenneth J.
dc.date.accessioned2020-01-17T22:39:50Z
dc.date.available2020-01-17T22:39:50Z
dc.date.created2019-03-29
dc.descriptionDue to copyright restrictions full text access from Treasures at UT Dallas is restricted to current UTD affiliates (use the provided Link to Article).
dc.description.abstractA novel copper(II) metal-organic framework (MOF) has been synthesized by modifying the reaction conditions of a 1D coordination polymer. The 1D polymer is built by the coordination between copper and 2,2′-(1H-imidazole-4,5-diyl)di-1,4,5,6-tetrahydropyrimidine (H-L1). The geometry of H-L1 precludes its ability to form extended 3D framework structures. By adding 1,4-benzenedicarboxylic acid (H 2 BDC), a well-studied linker in MOF synthesis, we achieved the transition from a 1D polymer chain into porous 2D layered structures. Hydrogen bonding between L1 and BDC directs the parallel stacking of these layers, resulting in a 3D structure with one-dimensional channels accessible by two different pore windows. The preferred growth orientation of the crystal produces prolonged channels and a disparity in pore size distribution. This in turn results in slow diffusion processes in the material. Furthermore, an isoreticular MOF was prepared by substituting the BDC linker by 2,6-naphthalenedicarboxylic acid (H₂NDC). © 2019 American Chemical Society.
dc.description.departmentSchool of Natural Sciences and Mathematics
dc.description.sponsorshipRobert A. Welch foundation (Grant No. AT-1153).
dc.identifier.bibliographicCitationVizuet, J. P., T. S. Howlett, A. L. Lewis, Z. D. Chroust, et al. 2019. "Transition from a 1D Coordination Polymer to a Mixed-Linker Layered MOF." Inorganic Chemistry 58(8): 5031-5041, doi: 10.1021/acs.inorgchem.9b00077
dc.identifier.issn0020-1669
dc.identifier.issue8
dc.identifier.urihttps://hdl.handle.net/10735.1/7157
dc.identifier.volume58
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.relation.urihttps://dx.doi.org/10.1021/acs.inorgchem.9b00077
dc.rights©2019 American Chemical Society
dc.source.journalInorganic Chemistry
dc.subjectCopper
dc.subjectPolymers
dc.titleTransition from a 1D Coordination Polymer to a Mixed-Linker Layered MOF
dc.type.genrearticle

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