Law and Disorder: Special Stacking Units—Building the Intergrowth Ce₆ Co₅ Ge₁₆

dc.contributor.ORCID0000-0003-4434-2160 (Chan, JY)
dc.contributor.ORCID0000-0002-2528-1967 (Felder, JB)
dc.contributor.ORCID0000-0001-7198-3559 (Weiland, A)
dc.contributor.ORCID0000-0003-2114-3644 (Walker, AV)
dc.contributor.authorFelder, Justin B.
dc.contributor.authorWeiland, Ashley
dc.contributor.authorHodovanets, H.
dc.contributor.authorMcCandless, George T.
dc.contributor.authorEstrada, Tania G.
dc.contributor.authorMartin, Thomas J.
dc.contributor.authorWalker, Amy V.
dc.contributor.authorPaglione, J.
dc.contributor.authorChan, Julia Y.
dc.contributor.utdAuthorFelder, Justin B.
dc.contributor.utdAuthorWeiland, Ashley
dc.contributor.utdAuthorMcCandless, George T.
dc.contributor.utdAuthorEstrada, Tania G.
dc.contributor.utdAuthorMartin, Thomas J.
dc.contributor.utdAuthorWalker, Amy V.
dc.contributor.utdAuthorChan, Julia Y.
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dc.description.abstractA new structure type of composition Ce₆ Co₅ Ge₁₆ was grown out of a molten Sn flux. Ce₆ Co₅ Ge₁₆ crystallizes in the orthorhombic space group Cmcm, with highly anisotropic lattice parameters of α = 4.3293(5) Å, b = 55.438(8) Å, and c = 4.3104(4) Å. The resulting single crystals were characterized by X-ray diffraction, and the magnetic and transport properties are presented. The Sn-stabilized structure of Ce₆ Co₅ Ge₁₆ is based on the stacking of disordered Ce cuboctahedra and is an intergrowth of existing structure types including AlB₂ , BaNiSn₃, and AuCu₃. The stacking of structural subunits has previously been shown to be significant in the fields of superconductivity, quantum materials, and optical materials. Herein, we present the synthesis, characterization, and complex magnetic behavior of Ce₆ Co₅ Ge₁₆ at low temperature, including three distinct magnetic transitions. © 2019 American Chemical Society.
dc.description.departmentSchool of Natural Sciences and Mathematics
dc.description.departmentErik Jonsson School of Engineering and Computer Science
dc.description.sponsorshipNational Science Foundation grant # DMR-1700030; CHE 1708259 and DMR 1609081; Gordon and Betty Moore Foundation’s EPiQS Initiative through Grant No. GBMF4419;
dc.identifier.bibliographicCitationFelder, J. B., A. Weiland, H. Hodovanets, G. T. McCandless, et al. 2019. "Law and Disorder: Special Stacking Units - Building the Intergrowth Ce₆ Co₅ Ge₁₆." Inorganic Chemistry 58(9): 6037-6043, doi: 10.1021/acs.inorgchem.9b00350
dc.publisherAmerican Chemical Society
dc.rights©2019 American Chemical Society
dc.source.journalInorganic Chemistry
dc.subjectIntermetallic compounds--Magnetic properties
dc.subjectChemical structure
dc.titleLaw and Disorder: Special Stacking Units—Building the Intergrowth Ce₆ Co₅ Ge₁₆


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