The Proof Is in the Powder: Revealing Structural Peculiarities in the Yb₃Rh₄Sn₁₃ Structure Type

Date
2018-09-12
item.page.orcid
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Soc Chemistry
item.page.doi
Abstract

Compounds adopting the Yb₃Rh₄Sn₁₃ structure type have drawn attention because of the revelation of exotic states such as heavy fermion behavior, superconductivity, charge density wave, and quantum critical behavior. The prototypical structure has historically been modeled with a primitive cubic space group, Pm3̅n; however, structural studies have led to the realization of disordered atomic sites, requiring lower symmetry models. We will review the low symmetry models required to describe the structural distortions in the related Yb₃Rh₄Sn₁₃ structure type. In addition, we present the structure determination of a new analogue, Lu₃Ir₄Ge₁₃, which adopts a new structural model in /4₁/amd.

Description
Full text access from Treasures at UT Dallas is available only to current UTD affiliates.
Keywords
Charge density waves, Crystals, X-ray crystallography, Complexity, Distortion, Chemistry, Crystallography
item.page.sponsorship
NSF-DMR1358975
item.page.rights
©2017 The Royal Society of Chemistry. This article may not be further made available or distributed.
Citation
Collections