Synthesis and Characterization of a Holmium 2,2′-bipyridine-5,5′-dicarboxylate MOF: Towards the Construction of a Suitable Holmium Carrier

dc.contributor.ORCID0000-0003-1142-3837 (Balkus, KJ)
dc.contributor.authorVizuet, Juan P.
dc.contributor.authorLewis, Abigail L.
dc.contributor.authorMcCandless, Gregory T.
dc.contributor.authorBalkus, Kenneth J.
dc.contributor.utdAuthorVizuet, Juan P.
dc.contributor.utdAuthorLewis, Abigail L.
dc.contributor.utdAuthorMcCandless, Gregory T.
dc.contributor.utdAuthorBalkus, Kenneth J.
dc.date.accessioned2020-12-18T22:19:42Z
dc.date.available2020-12-18T22:19:42Z
dc.date.issued2019-02
dc.descriptionDue to copyright restrictions and/or publisher's policy full text access from Treasures at UT Dallas is limited to current UTD affiliates (use the provided Link to Article).
dc.descriptionSupplementary material is available on publisher's website. Use the DOI link below.
dc.description.abstractBased on the 2,2′-bipyridine-5,5′-dicarboxylic acid ligand (H₂bpdc), a new metal-organic framework using holmium as the coordinating metal site was synthesized through a solvothermal reaction. The 3D compound {[Ho₂(bPdc)₃(DMF)₂] · 2(DMF)}ₙ (1) was characterized by single crystal X-ray diffraction, FTIR, TGA and PXRD. The coordination between H₂bpdc, the solvent, and holmium (CN = 7) allows for the construction of a MOF containing potentially free metal sites and uncoordinated N-donor sites. These features make this MOF an attractive holmium carrier for radiotherapeutic applications.
dc.description.departmentSchool of Natural Sciences and Mathematics
dc.description.sponsorshipRobert A. Welch foundation (Grant No. AT-1153)
dc.identifier.bibliographicCitationVizuet, Juan P., Abigail L. Lewis, Gregory T. McCandless, and Kenneth J., Jr. Balkus. 2019. "Synthesis and characterization of a holmium 2,2 '-bipyridine-5,5 '-dicarboxylate MOF: Towards the construction of a suitable holmium carrier." Polyhedron 159: 12-17, doi: 10.1016/j.poly.2018.11.036
dc.identifier.issn0277-5387
dc.identifier.urihttps://dx.doi.org/10.1016/j.poly.2018.11.036
dc.identifier.urihttps://hdl.handle.net/10735.1/9110
dc.identifier.volume159
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.rights©2018 Elsevier Ltd. All rights reserved.
dc.source.journalPolyhedron
dc.subjectMetal-organic frameworks
dc.subjectMetal-organic frameworks--Lanthanide
dc.subjectHolmium compounds
dc.subjectCrystals--Structure
dc.subjectCoordination polymers
dc.subjectNanoparticles
dc.titleSynthesis and Characterization of a Holmium 2,2′-bipyridine-5,5′-dicarboxylate MOF: Towards the Construction of a Suitable Holmium Carrier
dc.type.genrearticle

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