The Role of Crystal Growth Conditions on the Magnetic Properties of Ln₂Fe₄₋ₓCoₓSb₅ (Ln = La and Ce)

dc.contributor.ORCID0000-0001-7198-3559 (Weiland, A)
dc.contributor.ORCID0000-0002-9491-5177 (Lv, B)
dc.contributor.ORCID0000-0003-4434-2160 (Chan, JY)
dc.contributor.authorWeiland, Ashley
dc.contributor.authorLi, Sheng
dc.contributor.authorBenavides, Katherine A.
dc.contributor.authorBurnett, Joseph V.
dc.contributor.authorMilam-Guerrero, J.
dc.contributor.authorNeer, Abbey J.
dc.contributor.authorMcCandless, Gregory T.
dc.contributor.authorLv, Bing
dc.contributor.authorChan, Julia Y.
dc.contributor.utdAuthorWeiland, Ashley
dc.contributor.utdAuthorLi, Sheng
dc.contributor.utdAuthorBenavides, Katherine A.
dc.contributor.utdAuthorBurnett, Joseph V.
dc.contributor.utdAuthorNeer, Abbey J.
dc.contributor.utdAuthorMcCandless, Gregory T.
dc.contributor.utdAuthorLv, Bing
dc.contributor.utdAuthorChan, Julia Y.
dc.date.accessioned2020-01-29T21:15:41Z
dc.date.available2020-01-29T21:15:41Z
dc.date.issued2019-04-15
dc.descriptionDue to copyright restrictions full text access from Treasures at UT Dallas is restricted to current UTD affiliates (use the provided Link to Article).
dc.description.abstractSingle crystals of Ln₂Fe₄₋ₓCoₓSb_{5-y}Bi_y (Ln = La, Ce; 0 ≤ x ≤ 0.5; 0 ≤ y ≤ 0.2) were grown using Bi flux and self-flux methods. The compounds adopt the La₂Fe₄Sb₅ structure type with tetragonal space group I4/mmm. The La₂Fe₄Sb₅ structure type is comprised of rare earth atoms capping square Sb nets in a square antiprismatic fashion and two transition-metal networks forming a PbO-type layer with Sb and transition-metal isosceles triangles. Substituting Co into the transition-metal sublattice results in a decrease in the transition temperature and reduced frustration, indicative of a transition from localized to itinerant behavior. In this manuscript, we demonstrated that Bi can be used as an alternate flux to grow single crystals of antimonides. Even with the incorporation of Bi into the Sb square net, the magnetic properties are not significantly affected. In addition, we have shown that the incorporation of Co into the Fe triangular sublattice leads to an itinerant magnetic system. ©2019 American Chemical Society.
dc.description.departmentSchool of Natural Sciences and Mathematics
dc.description.sponsorshipNational Science Foundation (NSF-DMR-1700030 and NSF-DMR-1360863); U.S. Air Force Office of Scientific Research (AFOSR) (FA9550-15-1-0236 and FA9550-19-1-0037); Office of Naval Research (N00014-15-1-2411).
dc.identifier.bibliographicCitationWeiland, A., S. Li, K. A. Benavides, J. V. Burnett, et al. 2019. "The Role of Crystal Growth Conditions on the Magnetic Properties of Ln₂Fe₄₋ₓCoₓSb₅ (Ln = La and Ce)." Inorganic Chemistry 58(9): 6028-6036, doi: 10.1021/acs.inorgchem.9b00338
dc.identifier.issn0020-1669
dc.identifier.issue9
dc.identifier.urihttp://dx.doi.org/10.1021/acs.inorgchem.9b00338
dc.identifier.urihttps://hdl.handle.net/10735.1/7216
dc.identifier.volume58
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.rights©2019 American Chemical Society
dc.source.journalInorganic Chemistry
dc.subjectAntimony
dc.subjectCrystals--Structure
dc.subjectChemical Structure
dc.subjectMaterials--Magnetic properties
dc.subjectTransition temperature
dc.titleThe Role of Crystal Growth Conditions on the Magnetic Properties of Ln₂Fe₄₋ₓCoₓSb₅ (Ln = La and Ce)
dc.title.alternativeInorganic Chemistry
dc.type.genrearticle

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